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乔博课题组介绍

课题组长丨研究介绍丨代表性论文丨课题组成员

课题组长

乔博，助理教授、研究员

通讯地址：上海科技大学物质学院2号楼406B

电子邮件：qiaobo@shanghaitech.edu.cn

个人简历：

2007 - 2011 北京大学理学学士

导师：赵达慧、马玉国、赵新生

2012 - 2017 美国印第安纳大学博士

导师：Amar H. Flood

2017 - 2020 美国麻省理工学院博士后

合作导师：Jeremiah A. Johnson, Yang Shao-Horn

2020 至今上海科技大学物质科学与技术学院助理教授

研究介绍

本课题组研究超分子材料化学。我们基于非共价相互作用和选择性分子识别，设计新奇有趣的分子功能，并将这些分子功能引入宏观材料中，以实现传统材料所难以实现的新颖性质，以此解决在能源、环境、健康领域的重要问题。

目前，课题组主要从事以下四个方面的研究工作：

（1）调控和优化锂离子电解质材料中的分子间相互作用，开发高性能锂离子电解质

（2）利用非共价相互作用，开发光响应交联高分子网络，并对其结构、性质进行可逆调控

（3）利用统计学方法分析复杂材料中的分子间相互作用，实现数据驱动的理性设计，预测、优化材料性质

（4）基因传递高分子材料的精确合成

代表性论文

独立课题组

20. Shen, Z.-N.; Xu, Y.-X.; Wang, C.-Y.; Qiao, B.* Fine-tuning the thermal relaxtion dynamics of indigo-based photoswitches using selective non-covalent interactions without chemical modification, ChemPhotoChem, 2022, 6, e202200004 (Link).

Cover Feature:

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19. Fadler, R. E.; Al Quahabi, A.; Qiao, B.; Carta, V.; König, N. F.; Gao, X.; Zhao, W.; Zhang, Y.; Lutz, J.-F. Flood, A. H. Chain entropy beats hydrogen bonds to unfold and thread dialcohol phosphates inside cyanostar macrocycles to form [3]pseudorotaxanes, J. Org. Chem.2021, 86, 4532-4546.

18. Zhang, W.; Feng, S.; Huang, M.; Qiao, B.; Shigenobu, K.; Giordana, L.; Lopez, J.; Tatara, R.; Ueno, K.; Dokko, K.; Watanabe, M.; Shao-Horn, Y.; Johnson, J. A. Molecularly tunable polyanions for single-ion conductors and poly(solvate ionic liquids), Chem. Mater. 2021, 33, 524-534.

17. Benson, C. R.; Kacenauskaite, L.; VanDenburgh, K. L.; Zhao, W.; Qiao, B.; Sadhukhan, T.; Pink, M.; Chen, J.; Borgi, S.; Chen, C.-H.; Davis, B. J.; Simon, Y. C.; Raghavachari, K.; Laursen, B. W.; Flood, A. H. Plug-and-play optical materials from fluorescent dyes and macrocycles, Chem, 2020, 6, 1978-1997.

16. Qiao, B.†; Mohapatra, S.†; Lopez, J.; Leverick, G. M.; Tatara, R.; Shibuya, Y.; Jiang, Y.; France-Lanord, A.; Grossman, J. C.; Gomez-Bombarelli, R.; Johnson, J. A.; Shao-Horn, Y. Quantitative mapping of molecular substituents to macroscopic properties enables predictive design of oligoethylene glycol-based lithium electrolytes, ACS Cent. Sci. 2020, 6, 1115-1128. († equal contributions)

15. Zhao, W.; Tropp, J.; Qiao, B.; Pink, M.; Azoulay, J.; Flood, A. H. Tunable adhesion from stoichiometry-controlled and sequence-defined supramolecular polymers emerges hierarchically from cyanostar-stabilized anion-anion linkages, J. Am. Chem. Soc. 2020, 142, 2579-2591.

14. VanDenburgh, K. L.; Liu, Y.; Sadhukhan, T.; Benson, C. R.; Cox, N. M.; Erbas-Cakmak, S.; Qiao, B.; Gao, X.; Pink, M.; Raghavachari, K.; Flood, A. H. Multi-state amine sensing by electron transfers in a BODIPY probe, Org. Biomol. Chem. 2020, 18, 431-440.

13. Xue, W.; Shi, Z.; Huang, M.; Feng, S.; Wang, C.; Wang, F.; Lopez, J.; Qiao, B.; Xu, G.; Zhang, W.; Dong, Y.; Gao, R.; Shao-Horn, Y.; Johnson, J. A.; Li, J. FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries, Energy Environ. Sci. 2020, 13, 212-220

12. Huang, M.; Feng, S.; Zhang, W.; Lopez, J.; Qiao, B.; Tatara, R.; Giordano, L. Shao-Horn, Y.; Johnson, J. A. Design of S-substituted Fluorinated Aryl Sulfonamide Tagged (S-FAST) anions to enable new solvate ionic liquids for battery applications, Chem. Mater. 2019, 31, 7558-7564.

11. Zhao, W.; Qiao, B.; Tropp, J.; Pink, M.; Azoulay, J. D.; Flood, A. H. Linear supramolecular polymers driven by anion-anion dimerization of difunctional phosphate monomers inside cyanostar macrocycles, J. Am. Chem. Soc. 2019, 141, 4980-4989.

10. Qiao, B.; Leverick, G. M.; Zhao, W.; Flood, A. H.; Johnson, J. A.; Shao-Horn, Y. Supramolecular recognition of anions enhances conductivity and transference number of lithium in liquid electrolytes, J. Am. Chem. Soc. 2018, 140, 10932-10936.

9. Sheetz, E. G.; Qiao, B.; Pink, M.; Flood, A. H. Guest-triggered rotamers control stackable macrocycle complexes despite entropy penalty, J. Am. Chem. Soc. 2018, 140, 7773-7777.

8. Zhao, W.†; Qiao, B.†; Chen, C.-H.; Flood, A. H. High fidelity multi-state switching with anion-anion and acid-anion dimers of organophosphates in cyanostar complexes, Angew. Chem. Int. Ed. 2017, 56, 13083-13087. († equal contribution)

7. Qiao, B.; Hirsh, B. E.; Lee, S.; Pink, M.; Chen, C.-H.; Laursen, B. W.; Flood, A. H. Ion-pair oligomerization of chromogenic triangulenium cations with cyanostar-modified anions controls emission in hierarchical materials, J. Am. Chem. Soc. 2017, 139, 6226-6233.

6. Qiao, B.; Liu, Y.; Lee, S.; Pink, M.; Flood, A. H. High-yield synthesis and acid-base response of phosphate-templated [3]rotaxanes, Chem. Commun. 2016, 52, 13675-13678.

5. Qiao, B.; Anderson, J. R.; Pink, M.; Flood, A. H. Size-matched recognition of large anions by cyanostar macrocycles is saved when solvation-bias is avoided, Chem. Commun. 2016, 52, 8683-8686.

4. Qiao, B.; Sengupta, A.; Liu, Y.; McDonald, K. P.; Pink, M.; Anderson, J. R.; Raghavachari, K.; Flood, A. H. Electrostatic and allosteric cooperativity in ion-pair binding: a quantitative and coupled experiment–theory study with aryl-triazole-ether macrocycles, J. Am. Chem. Soc. 2015, 137, 9746-9757.

3. Hirsch, B. E.; McDonald, K. P.; Qiao, B.; Tait, S. L.; Flood, A. H. Crystal switching and anion binding in surface monolayers modulated by electric fields from scanning probes, ACS Nano 2014, 8, 10858-10869.

2. McDonald, K. P.; Qiao, B.; Twum, E. B.; Lee, S.; Gamache, P. J.; Chen, C.-H.; Yi, Y.; Flood, A. H. Chloride-binding poly(methyl methacrylate) copolymers bearing aryl-triazole side chains induce changes in polymer size and enhance salt extraction, Chem. Commun. 2014, 50, 13285-13288.

1. Hirsch, B. E. Lee, S.; Qiao, B.; Chen, C.-H.; McDonald, K. P.; Tait, S. L.; Flood, A. H. Anion-induced dimerization of 5-fold symmetric cyanostars in 3D crystalline solids and 2D self-assembled crystals, Chem. Commun. 2014, 69, 9827-9830.

本组成员